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A major challenge for breath research is the lack of standardization in sampling and analysis. To address this, a test that utilizes a standardized intervention and a defined study protocol has been proposed to explore disparities in breath research across different analytical platforms and to provide benchmark values for comparison. Specifically, the Peppermint Experiment involves the targeted analysis in exhaled breath of volatile constituents of peppermint oil after ingestion of the encapsulated oil. Data from the Peppermint Experiment performed by proton transfer reaction mass spectrometry (PTR-MS) and selected ion flow tube mass spectrometry (SIFT-MS) are presented and discussed herein, including the product ions associated with the key peppermint volatiles, namely limonene, α- and β-pinene, 1,8-cineole, menthol, menthone and menthofuran. The breath washout profiles of these compounds from 65 individuals were collected, comprising datasets from five PTR-MS and two SIFT-MS instruments. The washout profiles of these volatiles were evaluated by comparing the log-fold change over time of the product ion intensities associated with each volatile. Benchmark values were calculated from the lower 95% confidence interval of the linear time-to-washout regression analysis for all datasets combined. Benchmark washout values from PTR-MS analysis were 353 min for the sum of monoterpenes and 1,8-cineole (identical product ions), 173 min for menthol, 330 min for menthofuran, and 218 min for menthone; from SIFT-MS analysis values were 228 min for the sum of monoterpenes, 281 min for the sum of monoterpenes and 1,8-cineole, and 370 min for menthone plus 1,8-cineole. Large inter- and intra-dataset variations were observed, whereby the latter suggests that biological variability plays a key role in how the compounds are absorbed, metabolized and excreted from the body via breath. This variability seems large compared to the influence of sampling and analytical procedures, but further investigations are recommended to clarify the effects of these factors.
We compare results of simulations of solar facular-like conditions performed using the numerical codes MURaM and STAGGER. Both simulation sets have a similar setup, including the initial condition of ≈200 G vertical magnetic flux. After interpolating the output physical quantities to constant optical depth, we compare them and test them against inversion results from solar observations. From the snapshots, we compute the monochromatic continuum in the visible and infrared, and the full Stokes vector of the Fe i spectral line pair around 6301–6302 Å. We compare the predicted spectral lines (at the simulation resolution and after smearing to the HINODE SP/SOT resolution) in terms of their main parameters for the Stokes I line profiles, and of their area and amplitude asymmetry for the Stokes V profiles. The codes produce magnetoconvection with similar appearance and distribution in temperature and velocity. The results also closely match the values from recent relevant solar observations. Although the overall distribution of the magnetic field is similar in both radiation-magnetohydrodynamic (RMHD) simulation sets, a detailed analysis reveals substantial disagreement in the field orientation, which we attribute to the differing boundary conditions. The resulting differences in the synthetic spectra disappear after spatial smearing to the resolution of the observations. We conclude that the two sets of simulations provide robust models of solar faculae. Nevertheless, we also find differences that call for caution when using results from RMHD simulations to interpret solar observational data.
In the present work, using the recently introduced framework of local geometric deformations, special types of vector fields – so-called hidden Killing vector fields – are constructed, which solve the Killing equation not globally, but only locally, i.e. in local subregions of spacetime. Taking advantage of the fact that the vector fields coincide locally with Killing fields and therefore allow the consideration of integral laws that convert into exact physical conservation laws on local scales, balance laws in dynamical systems without global Killing symmetries are derived that mimic as closely as possible the conservation laws for energy and angular momentum of highly symmetric models. The utility of said balance laws is demonstrated by a concrete geometric example, namely a toy model for the binary merger of two extremal Reissner–Nordström black holes.
Wissensarbeiter:innen verbringen den überwiegenden Teil ihrer Arbeitszeit sitzend vor dem Computer. Die negativen Folgen von langem Sitzen für die Gesundheit sind bekannt: Zu langes Sitzen bedingt einen niedrigen Kalorienverbrauch, der Stoffwechsel und das Herz-Kreislaufsystem laufen auf Sparflamme. Entsprechend steigt das Risiko für Übergewicht, Diabetes, Bandscheibenvorfall und Herz-Kreislauf- Erkrankungen. Unter den Folgen von langem Sitzen leiden aber nicht nur die betroffenen Mitarbeiter:innen selbst, sondern auch deren Arbeitgeber:innen, weil Mitarbeiter:innen mit einem auf Bewegungsmangel zurückzuführenden reduzierten physischen und psychischen Wohlbefinden weniger produktiv und kreativ arbeiten bzw. aufgrund von Erkrankungen erst gar nicht arbeiten können. Der vorliegende Beitrag zeigt auf, wie Unternehmen durch das Setzen sanfter Bewegungszwänge, den Einsatz dynamischer Arbeitsstationen sowie die Integration niederschwelliger Fitnessmodule in die Bürolandschaft für mehr körperliche Aktivität im Arbeitsalltag sorgen können.
Talipot starch, a non-conventional starch source with a high yield (76%) from the stem pith of talipot palm (Corypha umbraculifera L.) was subjected to three different thermal treatments (dry-heat, heat-moisture and autoclave treatments) prior to phosphorylation. Upon dual modification of starch with thermal treatments and phosphorylation, the phosphorous content and degree of crosslinking significantly increased (p ≤ 0.05) and was confirmed by the increased peak intensity of P=O and P–O–C stretching vibrations compared to phosphorylated talipot starch in the FT-IR spectrum. The highest degree of crosslinking (0.00418) was observed in the autoclave pretreated phosphorylated talipot starch sample. Thermal pretreatment remarkably changed the granule morphology by creating fissures and grooves. The amylose content and relative crystallinity of all phosphorylated talipot starches significantly decreased (p ≤ 0.05) due to crosslinking by the formation of phosphodiester bonds, reducing the swelling power of dual-modified starches. Among all modified starches, dry-heat pretreated phosphorylated starch gel showed an improved light transmittance value of 28.4%, indicating reduced retrogradation tendency. Pasting and rheological properties represented that the thermal pretreated phosphorylated starch formed stronger gels that improved thermal and shear resistance. Autoclave treatment before phosphorylation of talipot starch showed the highest resistant starch content of 48.08%.
Marktrisikoprämie in Österreich: ein halbes Jahrhundert kein klarer Sieger bei Aktie vs Anleihe
(2021)
In tropical fruits such as durian (Durio zibethinus) and jackfruit (Artocarpus
heterophyllus), only one quarter to one third of the fruit is edible. Finding more
ways to industrially use the other components of the fruit can reduce the waste
burned or dumped in landfills. Another fruit tree of interest that can also grow
in Austria is the fig tree (Ficus carica). Currently, the fruits are the main product
of that plant; however, components in the latex of the tree are of interest too.
The latex is known to contain natural rubber, which could potentially be used for
industrial applications. Jackfruit trees also produce latex, which contains natural
rubber. In both cases, the natural rubber has different properties compared to
the conventionally used rubber from the rubber tree (Hevea brasiliensis). This
could provide new opportunities in various applications. Therefore, the purpose
of this research is to analyze the properties of the natural rubber obtained from
the jackfruit and fig trees. Additionally, durian fruit also produces a sticky liquid,
so the same experiments were also carried out with durian samples.
The experimental procedure included extraction with acetone and
cyclohexane as well as polymer length determination with gel permeation
chromatography and polymer analysis with differential scanning calorimetry.
The results show that in both jackfruit and fig tree latex, there is natural
rubber of similar polymer length. Durian pulp also contains a polymer; however,
with these experiments, it could not be identified. Further research is required to
identify the durian polymer and to confirm the results of this experiment.
On the surface, the process landscape for fixed income securities trading within most banks has changed only slightly in the past four decades. The value chain remains divided amongst front-, middle-, and back office, with IT in support. Front office negotiates deals with customers and other banks, middle office manages risks and reporting, and back office ensures that payments are made in exchange for a transfer of the bonds that have been traded. Though these processes have gradually migrated to electronic mediums, much of the work in all functional areas remains manual. But the advent of digital technologies, primarily process automation software and data integration in an open software architecture, allows banks to dramatically change how the processes along the value chain are carried out. Repetitive and predictable tasks can be performed by automated software, allowing humans to concentrate on complex activities that require flexibility and discretion. Those tasks that remain in the hands of humans can also be made more efficient by extracting data from software applications along the entire process chain and providing them to the human user at the right point in time in the right system.
A permutation can be locally classified according to the four local types: peaks, valleys, double rises and double falls. The corresponding classification of binary increasing trees uses four different types of nodes. Flajolet demonstrated the continued fraction representation of the generating function of local types, using a classical bijection between permutations, binary increasing trees, and suitably defined path diagrams induced by Motzkin paths.
The aim of this article is to extend the notion of local types from permutations to k-Stirling permutations (also known as k-multipermutations). We establish a bijection of these local types to node types of (k+1)-ary increasing trees. We present a branched continued fraction representation of the generating function of these local types through a bijection with path diagrams induced by Łukasiewicz paths, generalizing the results from permutations to arbitrary k-Stirling permutations.
We further show that the generating function of ordinary Stirling permutation has at least three branched continued fraction representations, using correspondences between non-standard increasing trees, k-Stirling permutations and path diagrams.
Stellar evolution models with entropy-calibrated mixing-length parameter: application to red giants
(2021)
Surface effects and turbulent pressure. Assessing the Gas-Γ1 and Reduced-Γ1 empirical models.
(2021)
In this work, the field of a gravitational shockwave generated by a massless point-like particle is calculated at the event horizon of a stationary Kerr–Newman black hole. Using the geometric framework of generalized Kerr–Schild deformations in combination with the spin-coefficient formalism of Newman and Penrose, it is shown that the field equations of the theory, at the event horizon of the black hole, can be reduced to a single linear ordinary differential equation for the so-called profile function of the geometry. This differential relation is solved exactly. Based on the results obtained, a physical interpretation is given for the found shockwave spacetime, and it is clarified how these results lead back to those of previous works on the subject, which deal with the much simpler cases of gravitational shockwaves in static black hole backgrounds.